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  1. A reaction or process in which heat is transferred to a system from its surroundings is endothermic. The first law of thermodynamics states that the energy of the universe is constant. The change in the internal energy of a system is the sum of the heat transferred and the work done.

    • Enthalpy

      The internal energy \(U\) of a system is the sum of the...

    • Calorimetry

      Because energy is neither created nor destroyed during a...

  2. The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities ...

  3. The first law of thermodynamics states that the change in internal energy of a system equals the net heat transfer into the system minus the net work done by the system. In equation form, the first law of thermodynamics is. ΔU = Q W. Here ΔU is the change in internal energy U of the system.

  4. chem.libretexts.org › Bookshelves › Physical_and_Theoretical_Chemistry_Textbook3.1: Calculation of Internal Energy Changes

    24 lis 2022 · Equation \ref{3.1.8} gave a mathematical definition of \(C_V\) as the partial derivative of a state function (the internal energy). But if heat capacities are coefficients, and coefficients are partial derivatives of state functions, how do we explain \(C_P\)?

  5. The change in the internal energy of the system, Δ U Δ U, is related to heat and work by the first law of thermodynamics: Δ U = Q W. Δ U = Q − W . It follows also that negative Q indicates that energy is transferred away from the system by heat and so decreases the system’s internal energy, whereas negative W is work done on the ...

  6. The first law of thermodynamics is a version of the law of conservation of energy specialized for thermodynamic systems. It is usually formulated by stating that the change in the internal energy of a closed system is equal to the amount of heat supplied to the system, minus the amount of work done by the system on its surroundings.

  7. The first law of thermodynamics states that the energy of the universe is constant. The change in the internal energy of a system is the sum of the heat transferred and the work done. The heat flow is equal to the change in the internal energy of the system plus the PV work done.

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