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27 paź 2017 · Below are tables that include determined pKa values for various acids as determined in water, DMSO and in the gas Phase. These tables are compiled in PDF files below. For a more comprehensive discussion on this topic, please see Acidity and Basicity by professor William Reusch, Michigan State University.
- Fundamentals of Organic Chemistry
This section of professor Reich's collection contains...
- Reduction and Oxidation
Reduction and Oxidation - Bordwell pKa Table - Organic...
- Pericyclic Reactions
Pericyclic Reactions - Bordwell pKa Table - Organic...
- Organometallic Chemistry
Organometallic Chemistry - Bordwell pKa Table - Organic...
- Reactive Intermediates
This page by Professor Hans Reich (UW-Madison) provides some...
- Named Reagents
Named Reagents - Bordwell pKa Table - Organic Chemistry Data
- Natural Product Syntheses
This set of pages is a collection of short natural product...
- Acronyms
lf the aldol reaction is considered a name reaction, and all...
- Fundamentals of Organic Chemistry
Acid H2S HS HCl –10 0 9.2 NC HBr –9 Br (H2SO4) H2CO3 6.4 HCO3 HCN H H pKa VALUES OF COMMON ORGANIC AND INORGANIC ACIDS R = alkyl group. H2O HO ROH RO RS H3CCH3 O H3CCH2 O NC CH3 NC CH2 RC CH RC C NH3 H2N R2CCH R2CCH RC H RC 15.7 16–17 Acid pKa Conjugate Base 11 20 25 25 38 44 ~ 48–53 (p. 2 of 2) NH4 H3N OH O 9.2 10 R R OO H H R R OO H 9 ...
Nucleosides 21 Carbon Acids 30,31 Special Table Heterocycles 22 Indicators 31 Acridine 23 References 32-34 Benzoquinoline 24 ... Organic Division Updated 4/7/2022 Page 1. pKa Data Compiled by R. Williams ACIDS Compound pK Ref. H3PO2 2.0, 2.23* 28 H2PO4– 7.21* 77 AgOH 3.96 4
Equilibrium pKa Table (DMSO Solvent and Reference) Hydrocarbons 20.117 21.822 22.522 17.317 Ph 18.019 26.122 Fluorenes X X = H 22.61 Me 22.31 Ph 17.91 tBu 24.421 SiMe3 21.5 26 SiPh3 18.6 26 = Fl-X
Table of Acids with Ka and pKa Values* CLAS * Compiled from Appendix 5 Chem 1A, B, C Lab Manual and Zumdahl 6th Ed. The pKa values for organic acids can be found in Appendix II of Bruice 5th Ed.
This table lists the dissociation (ionization) constants of over 1070 organic acids, bases, and amphoteric compounds. All data apply to dilute aqueous solutions and are presented as values of pKa, which is defined as the negative of the logarithm of the equi-librium constant Ka for the reaction. i.
D.H. Ripin, D.A. Evans 19-20 9 13 11 24.5 H2 ~36 *Values <0 for H2O and DMSO, and values >14 for water and >35 for DMSO were extrapolated using various methods. HCCH Substrate SubstrateSubstrate pKa H2O (DMSO) Substrate AMIDES HYDROCARBONS pKa H2OH(DMSO) pKa pKa2O (DMSO) H2O (DMSO) CH4 CH2=CHCH3 PhH CH2=CH2 PhCH3 Ph2CH2 Ph3CH (56) (44) (43)