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Abstract: Ionization of N2O4 in and on thin water films on surfaces is believed to be a key step in the hydrolysis of NO2 which generates HONO, a significant precursor to the OH free radical in the lower atmosphere.
1 maj 2009 · Ionization of N (2)O (4) in and on thin water films on surfaces is believed to be a key step in the hydrolysis of NO (2) which generates HONO, a significant precursor to the OH free radical...
23 kwi 2009 · Ionization of N 2 O 4 in and on thin water films on surfaces is believed to be a key step in the hydrolysis of NO 2 which generates HONO, a significant precursor to the OH free radical in the lower atmosphere.
15 sie 2020 · Procedure: Four glass tubes are sealed with NO 2 gas. The first tube is placed in a hot water bath. The second in ice-water. The third in flask with dry-ice/acetone. The fourth in liquid nitrogen. NO 2 is brown and N 2 O 4 is colorless. The intensity of the brown color decreases as the temperature decreases.
11 gru 2017 · The new mechanism allows N2O4 to react with H2O with a significantly lower barrier (< 13.1 kcal/mol) than the commonly known tight transition state (∼30-45 kcal/mol) by concurrent stretching of...
15 kwi 2024 · N2O4 is often used as an oxidizer in two-component liquid propulsion systems in the first and second stages of launch vehicles, owing to its high density, high specific impulse, and strong oxidizing properties.1 In the case of long-term storage, N2O4 absorbs H2O from the surrounding environment to form the N2O4(H2O)n system, which in turn genera...
The kinetics of the reactions of 2,6-di-t-butyl-4-methylphenol and 2,4,6-trimethylphenol with nitrogen dioxide in solution. Tetrahedron Letters 1986 , 27 (18) , 2037-2040.