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O 1)NaBH4 2)EtOH OH 3 4 However, unlikeGrignardreagents,Organocuprates alsoundergoa1,4-addtion: 1.(Et)2CuLi R 2.EtOH O R O 4 1 EtOH O HO OH H O O 1)LiAlH4 2)H+ O O HO O O 2CH3MgBr O 1) OH O 2)H+ HO O O H+ H2O HO H O Theacetal protecting group canthenberemoved under acidic conditions: + HO OH Aldehydes and ketones react with Grignard reagents ...
3 lut 2018 · 3.8 Aldehydes and Ketones Carbonyls: Aldehydes and Ketones. Carbonyls are compounds with a C=O bond. They can be either aldehydes or ketones If the C=O is on the end of the chain with an H attached it is an aldehyde. The name will end in –al CH3CHO ethanal CH3COCH3 If the C=O is in the middle of the chain it is a ketone The name will end in ...
Aldehydes and Ketones Cheat Sheet – A Beautiful PDF to Download. This cheat sheet study guide summarizes the reactions of aldehydes and ketones lay the foundation of understanding the nucleophilic addition reactions to many carbonyl compounds such as esters, acid chlorides, anhydrides, and others.
The simplest carbonyl compounds are aldehydes and ketones. ketone has two alkyl (or aryl) groups bonded to the carbonyl carbon. aldehyde has one alkyl (or aryl) group and one hydrogen bonded to the carbonyl carbon.
ALDEHYDES AND KETONES. 5.1 Introduction. H Aldehydes have a -C=O functional group. An aldehyde requires that at least one of the bonds on the C=O group is a hydrogen atom. When the carbonyl group (C=O) has two C atoms bonded to it is classified as a ketone. 5.2 Naming Aldehydes and Ketones. Systematic: methanal ethanal . propanal.
Extra Naming worksheet for Aldehydes and Ketones (Key) O (4S,5Z)-4,6-dimethyloct-5-en-2-one O (4S,5R)-4-isopropyl-5-propylcyclohex-2-enone H O OH O ... O OH O H (3R,4S,5S)-4,5-dihydroxy-3-methyl-6-oxoheptanal OH OH O O H (7S,8S,Z)-8-hydroxy-5,7-dimethyl-3-oxonon-4-enal. Title: Microsoft Word - Extra Naming worksheet for Aldehydes and Ketones ...
What are aldehydes and ketones? Aldehydes and ketones are simple compounds which contain a carbonyl group - a carbon-oxygen double bond. O. C. R H. 1) Aldehydes . General formula: RCHO or RCH=O. The aldehyde group is always at the end of a chain, so it will always take number 1.
