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O 1)NaBH4 2)EtOH OH 3 4 However, unlikeGrignardreagents,Organocuprates alsoundergoa1,4-addtion: 1.(Et)2CuLi R 2.EtOH O R O 4 1 EtOH O HO OH H O O 1)LiAlH4 2)H+ O O HO O O 2CH3MgBr O 1) OH O 2)H+ HO O O H+ H2O HO H O Theacetal protecting group canthenberemoved under acidic conditions: + HO OH Aldehydes and ketones react with Grignard reagents ...
3 lut 2018 · 3.8 Aldehydes and Ketones Carbonyls: Aldehydes and Ketones. Carbonyls are compounds with a C=O bond. They can be either aldehydes or ketones If the C=O is on the end of the chain with an H attached it is an aldehyde. The name will end in –al CH3CHO ethanal CH3COCH3 If the C=O is in the middle of the chain it is a ketone The name will end in ...
The simplest carbonyl compounds are aldehydes and ketones. ketone has two alkyl (or aryl) groups bonded to the carbonyl carbon. aldehyde has one alkyl (or aryl) group and one hydrogen bonded to the carbonyl carbon.
Chem 124 PAL Worksheet Aldehydes and Ketones Page 4 5. Evaluate each of the following sets of structures according to the given criterion. Circle your choice and give a brief explanation of your reasoning. a. Which is more reactive towards nucleophiles?
Aldehydes and Ketones Cheat Sheet – A Beautiful PDF to Download. This cheat sheet study guide summarizes the reactions of aldehydes and ketones lay the foundation of understanding the nucleophilic addition reactions to many carbonyl compounds such as esters, acid chlorides, anhydrides, and others.
ALDEHYDES AND KETONES. 5.1 Introduction. H Aldehydes have a -C=O functional group. An aldehyde requires that at least one of the bonds on the C=O group is a hydrogen atom. When the carbonyl group (C=O) has two C atoms bonded to it is classified as a ketone. 5.2 Naming Aldehydes and Ketones. Systematic: methanal ethanal . propanal.
Learning Guide for Chapter 19 - Aldehydes and Ketones. I. Introduction to aldehydes and ketones Properties, Bonding, Reactivity, Spectroscopy II. Nomenclature of aldehydes and ketones III. Synthesis of aldehydes and ketones IV. Oxidations and reductions V. Reactions of ketones and aldehydes with carbon nucleophiles Grignards and ...
